Synthesis and Characterization of Complexes of 3-(4'-Pryridyl)-4-Phenyl-Triazoline-5-Thione with some Non-transition Metals

eng Ansari Education and Research Society Journal of Ultra Chemistry 0973-3450 2319-8036 August 2009 5 2 279 283 juc 719 article Synthesis and Characterization of Complexes of 3-(4'-Pryridyl)-4-Phenyl-Triazoline-5-Thione with some Non-transition Metals R. N. Pandey 1 Prashasti Pandey 2 R. N. Sharma 2 P.G. Centre of Chemistry (M.U.) College of Commere PATNA - 800020 (INDIA) Department of Chemistry, K.N. Govt. P.G. College, Gyanpur (Bhadohi) 221304 (INDIA) <p>Complexes of 3-(4'-pyridyl)-4-Phenyltriazoline-5-thione have been prepared with Mg(II), Sn(II), Pb(II), Sb(II) and Bi(III) and characterized using various physico-chemical methods. The probable structures to these complexes have been assigned and mode of metal-ligand bonding has been investigated. The nature of shifting and change in intensity of all four thioamide bands of the ligand are used as diagnostic tool for metal-ligand bonding. The bonding through sulphur causes splitting of thio amide band IV. All the splitted bands are observed at lower frequencies.</p> https://journalofchemistry.org/paper/719/ Synthesis and Characterization Triazoline-5-Thione Non-transition