eng Ansari Education and Research Society Journal of Ultra Chemistry 0973-3450 2319-8036 June 2008 4 1 53 60 juc 760 article B. K. RAI (binodkr_rai@yahoo.co.in 1 ZAHID HUSSAIN 2 UPENDRA PRASAD SINGH 2 S. N. PRASAD 3 ANUKUL PRASAD 3 PREM MOHAN MISHRA 4 Department of Chemistry, L.N.T. College, Muzaffarpur (INDIA) Deptt. of Chemistry, A. College, Mahua (INDIA) Deptt. of Chemistry M.M. Das Mahila College, Srisia, Muzaffarpur (INDIA) Deptt. of Chemistry, M.I.S.M. College, Darbhnaga (INDIA) <p style="text-align: justify;">In the present paper we report the preparation and characterisation of a few homobinuclear metal complexes of the type [ML^1-2(H₂O)₂]₂X₂ with a pair of NNSO Schiff base, L¹ = 1-hydroxy-imino-1,2 diphenyl-3,4-diazo-5-amino-5-mercapto-2-pentene (HAPAME) and L² = 2-hydroxy-imino-3-methyl-4,5-diazo-6-mercapto-6-amino-3-hexane (HAMAME). M = Co(II), Ni(II) and Cu(II) and X = Cl^-, Br^-, NO₃^-, ClO₄^- and CH₃COO^-. Structural elucidation has been done on the basis of infrared spectra, electronic spectra, magnetic susceptibility, conductivity measurement and thermal analysis. On the basis of above observations, the ligands HAPAME/HAMAME coordinate to the metal ion in a tetradentate fashion and structure of the complexes proposed to be octahedral in nature.<br /> &nbsp;</p> https://journalofchemistry.org/paper/760/ Oxime Complexes