Kinetics of oxidation of b-alanine by chromic acid in presence hydrochloric acid in aqueous medium
Author & Affiliation:
Devendra P. Singh
Department of Chemistry, Govt. C.S.A.P.G., College, Sehore (INDIA)
Bijendra K. Mishra
Department of Chemistry, Cresent College of Technology, Bhopal (INDIA)
Rajesh Khare
Department of Chemistry, Govt. Sc. and Comm,. College Benazir, Bhopal (INDIA)
Keyword:
carbon dioxide
Issue Date:
August 2010
Abstract:
| The oxidation of ß-alanine by chromic acid in presence of hydrochloric acid in aqueous medium is reported here. The reaction is of first order with respect to substrate and total order is second with oxidant and substrate respectively. The oxidation reaction of b-alanine was studied at different acid concentrations. The products are acetaldehyde, carbon dioxide and ammonia. The rate of oxidation increases with increase in the concentration of acid. The dielectric constant and catalytic constant are calculated. The suitable mechanism has also been postulated |
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Pages:
187-192
ISSN:
2319-8036 (Online) - 0973-3450 (Print)
Source:
PDF:
DOI:
juc
Copy the following to cite this article:
D. P. Singh; B. K. Mishra; R. Khare, "Kinetics of oxidation of b-alanine by chromic acid in presence hydrochloric acid in aqueous medium", Journal of Ultra Chemistry, Volume 6, Issue 2, Page Number 187-192, 2018Copy the following to cite this URL:
D. P. Singh; B. K. Mishra; R. Khare, "Kinetics of oxidation of b-alanine by chromic acid in presence hydrochloric acid in aqueous medium", Journal of Ultra Chemistry, Volume 6, Issue 2, Page Number 187-192, 2018Available from: http://journalofchemistry.org/paper/613/
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