Some mixed ligand complexes of the type [M(MQTC)2X2] where M = Co(II), Ni(II) and Cu(II), MQTC = 3-methyl (N-O-Toludine)quinazolone thiosemicarbazone, X = Cl-, Br-, I-, NO3- and ClO4-. The ligand as well as metal complexes were characterized by elemental analysis, IR spectra, electronic spectra, magnetic suceptibility and molar conductance study. The molar conductance measurements of the complexes in DMF corresponds to non electrolytic in nature. On the basis of above observations the ligand MQTC behaves as bidentate manner and coordination proposes through azomethine N and thione sulphur atoms of thiosemicarbazone moiety. The remaining coordination sites are occupied by negative ions such as Cl-, Br-, I-, NO3- and ClO4-. The complexes were proposed to be octahedral in geometry on the basis of electronic and magnetic susceptibility value.
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B. K. Rai; Vinayak, "Spectral and physicochemical investigation of mixed ligand schiff base complexes of Co(II), Ni(II) and Cu(II) ", Journal of Ultra Chemistry, Volume 5, Issue 1, Page Number 67-72, 2018Copy the following to cite this URL:
B. K. Rai; Vinayak, "Spectral and physicochemical investigation of mixed ligand schiff base complexes of Co(II), Ni(II) and Cu(II) ", Journal of Ultra Chemistry, Volume 5, Issue 1, Page Number 67-72, 2018Available from: http://journalofchemistry.org/paper/682/