Some Five - coordinated organometallic Complexes of lridium (I) with Mixed- ligands
Five -coordinated mixed- ligands organometallic complexes of low - valent iridium(I)with triphenyl Phosphine (Pf3)and 3-(4-Pyridyl)-triazoline - 5- thione (PytTH)and its 4- Phenyl substituted derivative (PPytTH)have been prepared and characterized on the basis of micro -analytical, magnetic moment and electronic and IR Spectral data. Trans -[IrCl(CX)(Pf3)2] (X= O/S) undergo Substitution with triazole ligands giving [Ir(CX)(Pf3)2 Ligand] in which deprotonation of imino group of hydrogen occurs and ligand acts as bidentate N, S-donor. Metal-ligand vibrations in far IR region have been located and tentatively assigned.
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R. Pandey; D. P. Singh; P. Pande; G. Kumari, "Some Five - coordinated organometallic Complexes of lridium (I) with Mixed- ligands ", Journal of Ultra Chemistry, Volume 5, Issue 1, Page Number 79-82, 2018Copy the following to cite this URL:
R. Pandey; D. P. Singh; P. Pande; G. Kumari, "Some Five - coordinated organometallic Complexes of lridium (I) with Mixed- ligands ", Journal of Ultra Chemistry, Volume 5, Issue 1, Page Number 79-82, 2018Available from: http://journalofchemistry.org/paper/684/
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