Synthesis and Characterization of Complexes of 3-(4'-Pryridyl)-4-Phenyl-Triazoline-5-Thione with some Non-transition Metals
Author & Affiliation:
R. N. Pandey
P.G. Centre of Chemistry (M.U.) College of Commere PATNA - 800020 (INDIA)
Prashasti Pandey
Department of Chemistry, K.N. Govt. P.G. College, Gyanpur (Bhadohi) 221304 (INDIA)
R. N. Sharma
Department of Chemistry, K.N. Govt. P.G. College, Gyanpur (Bhadohi) 221304 (INDIA)
Keyword:
Synthesis and Characterization, Triazoline-5-Thione , Non-transition
Issue Date:
August 2009
Abstract:
Complexes of 3-(4'-pyridyl)-4-Phenyltriazoline-5-thione have been prepared with Mg(II), Sn(II), Pb(II), Sb(II) and Bi(III) and characterized using various physico-chemical methods. The probable structures to these complexes have been assigned and mode of metal-ligand bonding has been investigated. The nature of shifting and change in intensity of all four thioamide bands of the ligand are used as diagnostic tool for metal-ligand bonding. The bonding through sulphur causes splitting of thio amide band IV. All the splitted bands are observed at lower frequencies.
Pages:
279-283
ISSN:
2319-8036 (Online) - 0973-3450 (Print)
Source:
PDF:
DOI:
juc
Copy the following to cite this article:
R. N. Pandey; P. Pandey; R. N. Sharma, "Synthesis and Characterization of Complexes of 3-(4'-Pryridyl)-4-Phenyl-Triazoline-5-Thione with some Non-transition Metals", Journal of Ultra Chemistry, Volume 5, Issue 2, Page Number 279-283, 2018Copy the following to cite this URL:
R. N. Pandey; P. Pandey; R. N. Sharma, "Synthesis and Characterization of Complexes of 3-(4'-Pryridyl)-4-Phenyl-Triazoline-5-Thione with some Non-transition Metals", Journal of Ultra Chemistry, Volume 5, Issue 2, Page Number 279-283, 2018Available from: http://journalofchemistry.org/paper/719/
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