Studies on Mixed-Ligand Complexes of In(III) with some amino acids and Phthalic acid at DME : A Polarographic Approach
A polarographic study of In(III) with some amino acids and Phthalic acid have been carried out separately at ionic strength kept constant (µ = 1) by using KCl at 298K. DeFord and Hume's method is used to calculate the stepwise formations constants of simple systems (In-amino acids and In-Phthalic acid) while the stability constants of mixed complexes have been evaluated by the method of Schaap & McMaster's. The reduction of In(III) ion is found to be quasireversible and diffusion controlled involving three electrons in each case. The statistical and electrostatic effects have also been discussed by using these stability constants. The mixing constant (Km) and stabilization constant (Ks) were measured for comparative study of simple and mixed ligand complexes.
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C. Karadia; O. Gupta, "Studies on Mixed-Ligand Complexes of In(III) with some amino acids and Phthalic acid at DME : A Polarographic Approach ", Journal of Ultra Chemistry, Volume 4, Issue 2, Page Number 237-244, 2018Copy the following to cite this URL:
C. Karadia; O. Gupta, "Studies on Mixed-Ligand Complexes of In(III) with some amino acids and Phthalic acid at DME : A Polarographic Approach ", Journal of Ultra Chemistry, Volume 4, Issue 2, Page Number 237-244, 2018Available from: http://journalofchemistry.org/paper/735/
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