Complexes of the type,R₃SnCl.L(where R= -C₆H₅ and L= Et₂NH, Pr₂NH and Bz₂NH) were obtained. Complexes of the type, R₂SnCl₂.2L (where R=-CH₃ and L=Et₂NH, Pr₂NH, Bz₂NH and (CH₂CH₂OH)₂NH; R=-C₄H₉ and L= Et₂NH and Pr₂NH and where R= C₆H₅ and L= Bz₂NH) were formed. Complexes of the type, R₂SnCl₂.L(where R= -C₆H₅ and L= Et₂NH and Pr₂NH; and where R= -CH₃ and L= MePhNH) were also formed. Complexes of the type, ROSnCl₃.2L (where R=-CH₃, -C₂H₅ and t- C₄H₉ and L= Et₂NH, Pr₂NH and Bz₂NH; and also where R= -CH₃ and -C₂H₅ with (CH₂CH₂OH)₂NH and MePhNH) were prepared. Complex of the type, ROSnCl₃.L (where R= t-C₄H₉ and L= MePhNH) was also isolated. Infrared spectral studies were carried out.