Pyridinium Fluorochromate Oxidation of Acetophenone oxime in Acid Medium
Author & Affiliation:
V. M. KAMBLE
Department of Chemistry, M.U, Mahavidyalaya, Udgir-413517 (Dist Latur) INDIA
S. B. JOSHI
Department of Chemistry, M.U, Mahavidyalaya, Udgir-413517 (Dist Latur) INDIA
Keyword:
pyridinium fluorochromate, oxidation, acetophenoneoxime
Issue Date:
June 2008
Abstract:
The Kinetics of the oxidation of acetophenoneoxime by pyridinium fluorochromate has been studied in acetic acid medium. The reaction has unit dependence on each of the PFC [H+] and first order with respect to substrate. The effect of temperature, solvent and neutral salt has been studied. The rate increases with increase in concentration of hydrogen ions, the activation energy and other thermodynamic parameters are determined and a possible mechanism has been proposed.
Pages:
137-141
ISSN:
2319-8036 (Online) - 0973-3450 (Print)
Source:
PDF:
DOI:
juc
Copy the following to cite this article:
V. M. Kamble; S. B. Joshi, "Pyridinium Fluorochromate Oxidation of Acetophenone oxime in Acid Medium", Journal of Ultra Chemistry, Volume 4, Issue 1, Page Number 137-141, 2018Copy the following to cite this URL:
V. M. Kamble; S. B. Joshi, "Pyridinium Fluorochromate Oxidation of Acetophenone oxime in Acid Medium", Journal of Ultra Chemistry, Volume 4, Issue 1, Page Number 137-141, 2018Available from: http://journalofchemistry.org/paper/777/
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