Kinetics and mechanism of oxidation of arginine by Cr (VI) has been studied. The main product of oxidation is g-guanidino butanaldehyde. The reaction is first order to arginine and first order with respect to Cr (VI) respectively. The reaction is acid catalysed. The dielectric constant of the medium on the rate have no effect. The activation energy is computed with respect to slow step of the mechanism.
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A. Ansari; D. Singh; B. Mishra, "KINETIC INVESTIGATIONS OF OXIDATION OF ARGININE BY CHROMIC ACID IN PRESENCE OF HYDROCHLORIC ACID", Journal of Ultra Chemistry, Volume 1, Issue 2, Page Number 95-100, 2018Copy the following to cite this URL:
A. Ansari; D. Singh; B. Mishra, "KINETIC INVESTIGATIONS OF OXIDATION OF ARGININE BY CHROMIC ACID IN PRESENCE OF HYDROCHLORIC ACID", Journal of Ultra Chemistry, Volume 1, Issue 2, Page Number 95-100, 2018Available from: http://journalofchemistry.org/paper/849/