P.G. Centre of Chemisry (M.U.) College of Commerece, Patna India
Email:- rameshwarnath.pandey@yahoo.com
Low-valent organometallic derivatives of rhodium(I) with 4-amino-5-mercapto-3-substitution-1,2,4-triazole have been isolated from displacement reaction of Rh(Pf3)3Cl with methyl and ethyl substitution of ligand in benzene medium. Oxidation state of metals in these compounds is determined iodometrically. Most probable square planar configuration for Rh(I) have been assigned using various physico-chemical data. Metal-ligand vibrations in the far-infrared spectra of complexes have been reasonably assigned.
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R.N. Pandeya and R.N. Sharma* , "Low-valent organometallic derivatives of rhodium(I) with 4-amino-5-mercapto-3-substituted-1,2,4-triazoles ", Journal of Ultra Chemistry, Volume 7, Issue 3, Page Number 365-368, 2016Copy the following to cite this URL:
R.N. Pandeya and R.N. Sharma* , "Low-valent organometallic derivatives of rhodium(I) with 4-amino-5-mercapto-3-substituted-1,2,4-triazoles ", Journal of Ultra Chemistry, Volume 7, Issue 3, Page Number 365-368, 2016Available from: http://journalofchemistry.org/paper/515/