Low-valent organometallic derivatives of palladium(0) and platinum(0) with 4-amino-5-mercapto-3- substituted-1,2,4-triazoles
Author & Affiliation:
R.N. Pandey
Department of Chemistry, K.N. Govt. P.G. College Gyanpur, Bhadohi -221304 (INDIA)
R.N. Sharma
P.G. Centre of Chemistry (M.U.) College of Commerce, Patna -800020 INDIA
Keyword:
determined iodometrically
Issue Date:
December 2010
Abstract:
Low-valent organometallic derivatives of palladium(0) and platinum(0) with 4-amino-5-mercapto-3-substitution-1,2,4-triazole have been isolated from displacement reaction of M(p3)4 (M=Pd/Pt) and Rh(pf3)3 Cl with methyl and ethyl substitution of ligand in benzene medium. Oxidation state of metals in these compounds is determined iodometrically. Most probable tetrahedral structure for Pd(0) and Pt(0) have been assigned using various physico-chemical data. Metal-ligand vibrations in the far-infrared spectra of complexes have been reasonably assigned.
Pages:
361-364
ISSN:
2319-8036 (Online) - 0973-3450 (Print)
Source:
PDF:
DOI:
juc
Copy the following to cite this article:
R. Pandey; R. Sharma, " Low-valent organometallic derivatives of palladium(0) and platinum(0) with 4-amino-5-mercapto-3- substituted-1,2,4-triazoles", Journal of Ultra Chemistry, Volume 6, Issue 3, Page Number 361-364, 2018Copy the following to cite this URL:
R. Pandey; R. Sharma, " Low-valent organometallic derivatives of palladium(0) and platinum(0) with 4-amino-5-mercapto-3- substituted-1,2,4-triazoles", Journal of Ultra Chemistry, Volume 6, Issue 3, Page Number 361-364, 2018Available from: http://journalofchemistry.org/paper/598/
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